25690

Image

1 of 1

25690

Sigma-Aldrich

 

Chloroform

puriss. p.a., ACS reagent, ≥99.8% (chloroform + ethanol, GC)

Synonym:Methylidyne trichloride, Trichloromethane
CAS Number:67-66-3
Linear Formula:CHCl3
Molecular Weight:119.38
Beilstein Registry Number:1731042
MDL number:MFCD00000826
PubChem Substance ID:24855558

Related Products

Reviews

Description

Other NotesSales restrictions may apply

Properties

gradeACS reagent
vapor density4.1 (vs air)
vapor pressure160 mmHg ( 20 °C)
 puriss. p.a.
assay≥99.8% (chloroform + ethanol, GC)
contains~1% ethanol as stabilizer
total impurities≤0.0002% ketone (as CH3COCH3)
 ≤0.001% free acid (as HCl)
 ≤0.02% water
 <0.0001% aldehyde (as CH3CHO)
 <0.0001% formaldehyde (HCHO)
evapn. residue ≤0.001%
refractive indexn20/D 1.445(lit.)
 n20/D 1.445
bp60.5-61.5 °C(lit.)
mp−63 °C(lit.)
density1.492 g/mL at 25 °C(lit.)
cation tracesAl: ≤0.5 mg/kg
 Ba: ≤0.1 mg/kg
 Bi: ≤0.1 mg/kg
 Ca: ≤0.5 mg/kg
 Cd: ≤0.05 mg/kg
 Co: ≤0.02 mg/kg
 Cr: ≤0.02 mg/kg
 Cu: ≤0.02 mg/kg
 Fe: ≤0.1 mg/kg
 K: ≤0.5 mg/kg
 Li: ≤0.1 mg/kg
 Mg: ≤0.1 mg/kg
 Mn: ≤0.02 mg/kg
 Mo: ≤0.1 mg/kg
 Na: ≤0.5 mg/kg
 Ni: ≤0.02 mg/kg
 Pb: ≤0.05 mg/kg
 Sr: ≤0.1 mg/kg
 Zn: ≤0.1 mg/kg
suitabilitynegative for detection of free chlorine
 negative for detection of phosgene

Safety

Personal Protective EquipmentEyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US)
Hazard CodesXn
Risk Statements22-38-40-48/20/22
Safety Statements36/37
RIDADRUN1888 6.1/PG 3
WGK Germany3
RTECSFS9100000

References

MerckMerck 13,2160
BeilsteinBeil. 1,IV,42
FieserFieser 1,29 / Fieser 1,130 / Fieser 1,30 / Fieser 3,140 / Fieser 4,22 / Fieser 5,28 / Fieser 8,92 / Fieser 12,517 / Fieser 14,167 / Fieser 15,84
referenceAldrich MSDS 1, 405:C / Corp MSDS 1 (1), 786:C / FT-IR 1 (1), 83:A / FT-IR 2 (1), 117:D / FT-NMR 1 (1), 122:A / IR-Spectra (2), 49:E / IR-Spectra (3), 51:G / NMR-Reference 2 (1), 81:C / RegBook 1 (1), 81:D / Sax 6, 722 / Structure Index 1, 9:D:10 / Vapor Phase 3, 116:C